Stability Range Research Articles

Paddy straw saccharification using immobilized laccase on magnetized multiwall carbon nanotubes.

The effective recovery of the immobilized enzymes using magnetic carriers has led to growing interest in this technology. The objective of this research was to evaluate the efficiency of immobilized laccase on magnetized multiwall carbon nanotubes (m-MWCNTs) in terms of stability and reusability. Laccases were efficiently adsorbed onto magnetized multiwall carbon nanotubes (m-MWCNTs) synthesized using water. The concentration of 7mg laccase/mL was found to be ideal for immobilization. The optimal activity of both free and immobilized laccases was observed at pH 5, while for the latter, the optimal temperature was shifted from 40 to 50°C. Compared to the free laccase, the immobilized laccase exhibited a greater range of stability at more extreme temperatures. At the fourth cycle of reactions, the immobilized laccase exhibited more than 60% relative activity in terms of reusability. Based on the fourier-transform infrared spectroscopy (FTIR) peak at 2921cm-1, saccharification of paddy straw using immobilized laccase verified lignin degradation. The easy recovery of the immobilized laccase on m-MWCNTs lends credence to its potential use in biomass hydrolysis.

Thermoelectric transport and Rashba spin-splitting of black arsenic phosphorus under strain regulation

Abstract The Rashba spin-splitting and thermoelectric transport of two-dimensional black arsenic phosphorus (2D B-AsP) under strain control are studied using non-equilibrium Green’s function and first principles calculations. Firstly, we determine the stability range of 2D B-AsP under strain conditions, with biaxial strain ranging from −2% to +5% and uniaxial strain ranging from −4% to +5%. Secondly, we analyze at the point Γ under strain within the range of −1% to +2%, and find the spin-splitting coefficient decreases with increasing strain. Thirdly, we discuss the effects of applying strain and changing temperature on 2D B-AsP thermoelectric transport. When the uniaxial compression strain is −4%, the ZT coefficient increases by 12.91%, and increases by 48.8% at a temperature of 400 K. Finally, when two external conditions exist simultaneously, the ZT coefficient of the material increases by 44.6%. The research results demonstrate the potential applications of 2D B-AsP in spintronics and thermoelectricity.

A novel locally resonance metamaterial cylindrical shell with tower-shaped lattice for broadband vibration suppression

Vibration issues in cylindrical shells are prevalent in engineering applications and can significantly impact the operational performance of systems. To address these challenges, this paper designs a novel local resonance tower structure, and establishes an analytical model to investigate vibration characteristics of the metamaterial cylindrical shell. Based on the model, a gradient design strategy is proposed to improve vibration suppression properties over a wide frequency range. Firstly, the governing equations of the cylindrical shell are derived and the dispersion analysis is conducted to predict the bandgap boundaries using the extended plane wave expansion (EPWE) method. Then, for a finite-period metamaterial cylindrical shell with specific boundary conditions, the frequency response of the structure is obtained by finite element calculations to show the bandgap behavior. The results of these two methods are basically the same. In addition, the effects of frequency spacing, damping and array period on the vibration characteristics are considered comprehensively. The results show that a wider and more stable attenuation range can be obtained by reasonably adjusting these three parameters. Finally, the comparison between experimental and numerical calculations verify that the tower structure is effective, and that the proposed design strategy can broaden the vibration attenuation region.

Advancing Detectivity and Stability of Near-Infrared Organic Photodetectors via a Facile and Efficient Cathode Interlayer.

Near-infrared (NIR) organic photodetectors (OPDs) are pivotal in numerous technological applications due to their excellent responsivity within the NIR region. Polyethylenimine ethoxylated (PEIE) has conventionally been employed as an electron transport layer (hole-blocking layer) to suppress dark current (JD) and enhance charge transport. However, the limitations of PEIE in chemical stability, processing conditions, environmental impact, and absorption range have spurred the development of alternative materials. In this study, we introduced a novel solution: a hybrid of sol-gel zinc oxide (ZnO) and N,N'-bis(N,N-dimethylpropan-1-amine oxide)perylene-3,4,9,10-tetracarboxylic diimide (PDINO) as the electron transport layer for NIR-OPDs. Our fabricated OPD exhibited significantly improved responsivity, reduced internal traps, and enhanced charge transfer efficiency. The detectivity, spanning from 400 to 1100 nm, surpassed ∼5 × 1012 Jones, reaching ∼1.1 × 1012 Jones at 1000 nm, accompanied by an increased responsivity of 0.47 A/W. Also, the unpackaged OPD remarkedly demonstrated stable JD and external quantum efficiency (EQE) over 1000 h under dark storage conditions. This innovative approach not only addresses the drawbacks of conventional PEIE-based OPDs but also offers promising avenues for the development of high-performance OPDs in the future.

A bidirectional resonant CLLC converter combining three‐level characteristic and bipolar DC structure

SummaryIn order to meet the efficient and convenient usage requirements for bidirectional DC‐DC converters in some fields such as DC microgrids and vehicle power conversion systems, a bidirectional resonant CLLC converter combining three‐level characteristic and bipolar DC structure is used and analyzed in this paper. A three‐level topology is adopted in the resonant CLLC converter, which can achieve stable and wider range voltage regulation through the frequency adjustment combined with duty cycle and phase shift modulation, and can also increase the flexibility of control strategy. The application of bipolar DC structure enables this resonant CLLC converter to have multi‐port on one side, and the method of using two interleaved inductors combined with synchronous rectification enables the output voltage of the converter to maintain a certain balance. In this paper, the voltage gains and running states of the three‐level regulation method are analyzed, and then these operation modes and the bipolar DC voltage balance effect of the converter under synchronous rectification control are verified by the experiment results.

Excellent energy storage properties and multi-scale regulation mechanism of Sr(Zr0.5Ti0.5)O3-(Na0.5Bi0.5)0.94Ba0.06TiO3 ceramics

With the rapid advancement of energy storage technologies, dielectric capacitor materials with the outstanding recoverable energy density and power density have garnered significant attention from researchers in the past decades. In this study, (1-x) (Na0.5Bi0.5)0.94Ba0.06TiO3-xSr(Zr0.5Ti0.5)O3 ceramics were prepared via a solid-state reaction method, and the impact of composition on their structure, energy storage performance and stability were investigated. The results revealed that the introduction of Sr(Zr0.5Ti0.5)O3 induced the ferroelectric-relaxor transformation of (Na0.5Bi0.5)0.94Ba0.06TiO3 ceramics, leading to the destruction of the long-range ferroelectric order and the formation of polar nanoregions. In addition, the 0.7(Na0.5Bi0.5)0.94Ba0.06TiO3–0.3Sr(Zr0.5Ti0.5)O3 ceramic exhibited the optimal comprehensive energy storage performance: its recoverable energy storage Wrec attained 8.19 J/cm3 at 650 kV/cm, while the energy storage efficiency η was 85.6 %. Meanwhile, it displayed exceptionally high power density (315.7 MW/cm3) and charge-discharge rate (t0.9 = 50.4 ns). Moreover, this ceramic demonstrated the impressive energy storage performance, in particular, good temperature stability across a wide range of temperatures (20–140 °C), frequency stability (1–200 Hz), and fatigue resistance (1–106 cycles). Finite element analysis showed an enhancement in the breakdown field strength of the ceramics was attributed to the reduction in grain size. First-principles calculations revealed that the band gap increased after adding Sr and Zr elements, and the interactions between the states of O 2p and Ti 3d, Zr 3d, Bi 6p may serve as the microscopic origin of electron energy level polarization and enhanced dielectric performance. Thus, the ceramics have great potential for the application in high-power pulsed electronic systems.

Segregation-dependent mechanical stability of reverted austenite and resultant tensile properties of Co-free maraging steel fabricated by wire-arc directed energy deposition

The segregation-dependent mechanical stability of reverted austenite (RA) and resultant tensile properties was investigated on Co-free maraging steel fabricated by wire-arc directed energy deposition (DED). The results showed that the segregation in the interdendritic regions enabled the formation of gradient reverted austenite in Co-free maraging steel fabricated by wire-arc DED when subjected to aging heat treatment. The content and mechanical stability of reverted austenite and resultant tensile properties were strongly dependent on the degree and compositional gradient of segregation in the interdendritic regions as well as the post heat treatment process. The reverted austenite with compositional gradient inherited from the segregation, transformed into martensite successively from the edge to the interior within individual reverted austenite grain at different strain levels. Besides, the variations in the degree and compositional gradient of segregation in the interdendritic regions widened the range the mechanical stability of the reverted austenite and thereby activating martensite transformation over a broad strain regime. Annealing process prior to aging could modify the degree and compositional gradient of segregation in the interdendritic regions and accordingly tune the content and the range of mechanical stabilities of reverted austenite grains, thus attaining a gradual and consistent transformation induced plasticity effect over whole deformation regime and thereby increasing ductility without sacrificing strength of Co-free maraging steel fabricated by wire-arc DED.

Stable and wide temperature range superelasticity in an Mo-doped nanocrystalline Ni-Ti-Mo shape memory alloy

The phase transformation and superelastic behavior of nanocrystalline Ni48Ti50Mo2 alloy wires were investigated. Nanocrystalline (NC) alloys were obtained via severe plastic deformation of cold-drawing followed by annealing at low temperatures. The results indicate that the NC Ni48Ti50Mo2 undergoes a single-step B2→R phase transformation and a two-step B2→R→B19' phase transformation in coarse crystals (CG). The NC alloy wire exhibits 8% recoverable strain under a tensile stress of 1.1 Ga and superelasticity exists in a wide temperature range from -60 °C to 100 °C. After 50 cycles of tension fatigue testing, the superelastic upper plateau stress reduction rate is 7% with almost no residual strain accumulation, which has excellent superelastic stability compared with fine crystals and coarse crystals. Transmission electron microscope (TEM) reveals an average grain size of 20 nm. The stable superelasticity is attributed to the nanocrystalline reinforced matrix, which hinders dislocation generation and slip.

Experimental Study on Ultra-Low Concentration Methane Regenerative Thermal Oxidation

As a major coal country, China faces the issue of significant gas emissions during the coal mining process. This study aims to improve the utilization efficiency of mine gas, reduce greenhouse gas emissions, and promote the low-carbon and green transformation of the coal industry. A 10 kW gas regenerative thermal oxidizer (RTO) experimental system was constructed. The effects of initial methane concentration, low-temperature flue gas proportion, and operating load on combustion temperature, methane oxidation rate, high-temperature flue gas energy, and system thermal efficiency were studied. The results show that when the combustion temperature is below 600 °C, the CH4 combustion reaction cannot proceed effectively, and the system temperature continuously decreases and cannot be maintained stably. The experiment determines the stable operating methane concentration range of the RTO. In this experimental system, the lower limit of the initial methane concentration is 0.28%, corresponding to an 86% methane oxidation rate. As the initial methane concentration decreases, the combustion temperature also decreases, and the methane oxidation rate follows suit. The higher the low-temperature flue gas proportion, the higher the combustion temperature, and the system’s thermal efficiency and output heat decrease with the increase in the low-temperature flue gas proportion. This experiment explores multiple factors affecting regenerative thermal oxidation, providing a basis for ensuring the safe and stable operation of the system and its optimization. Improving the thermal insulation and heat exchange performance of the storage body can expand the lower limit of the initial methane concentration, thereby increasing the stability and thermal efficiency of the system.

The complexity analysis of decision-making for horizontal fresh supply chains under a trade-off between fresh-keeping and carbon emission reduction

This study primarily focuses on the impact of carbon emissions generated during the fresh product fresh-keeping process on the traditional fresh supply chain (FSC1) and the low-carbon fresh supply chain with emission reduction behavior (FSC2). Its objective is to investigate how these supply chains dynamically adjust the production quantity, fresh-keeping level, and emission reduction level of fresh products when constrained by the dual-carbon policy. The decision competition model between the two supply chains was explored under two scenarios: the horizontal Nash (HN) game and the long-term Stackelberg (LS) game, wherein FSC1 assumes the role of the leader. The findings indicate that as the carbon tax and carbon trading price increase, the fresh supply chain tends to decrease fresh-keeping intensity while increasing investment in emission reduction. Carbon emissions generated during the fresh product fresh-keeping process have a smaller impact on FSC2's profit than on FSC1, and FSC2 exhibits stronger adaptability under the dual-carbon policy. Irrespective of the game structure, if the adjustment speed of FSC1's production decision exceeds the stable range, its own profit will decrease while the other party's profit will increase. However, if the adjustment speed of FSC2's production decision surpasses the stable range, it will lead to a decrease in profits for both sides. Interestingly, in the LS game, when the adjustment speed of FSC1's production decision exceeds the stable range, FSC1 demonstrates a leader advantage and experiences a rapid increase in profit as the adjustment speed of FSC2's production decision increases, this phenomenon suggests that in the LS game, the leader prevails amidst market chaos.

Distribution Dynamics of Diplopanax stachyanthus Hand.-Mazz. (Mastixiaceae) and Its Implications in Relict Mastixioid Flora Conservation

Climate is a key driver shaping the distribution pattern of organisms. Cenozoic climate change has led to extensive biota turnover. Untangling the distribution dynamics of a representative lineage of flora can provide deep insights into biodiversity conservation. Diplopanax is a notable relict lineage of the Tertiary mastixioid flora with abundant fossils in the Northern Hemisphere. Diplopanax stachyanthus Hand.-Mazz. is a representative relic lineage of the mastixioid flora, which was once widespread in the Northern Hemisphere of the early Tertiary period, but with only endemic distribution in the (sub)tropical humid forests of East Asia. It offers a unique chance to understand how climatic drivers shape the Boreotropical flora. In this research, we investigated the distribution dynamics of D. stachyanthus at the last glacial maximum (LGM), mid-Holocene (MH), current, and three periods of the future (2041–2060, 2061–2080, and 2081–2100) at four shared socio-economic emissions scenarios pathways. Our results indicated that the Precipitation of the Wettest Quarter (32.6%), the Precipitation of the Driest Quarter (21.2%), and the Precipitation of the Coldest Quarter (17.3%) are the key factors affecting its distribution. The current high suitable distribution areas are primarily in southern China and northern Indo-China. The enforced winter monsoon seasons in East Asia since the late Pliocene period are the key climatic drivers reducing its once widespread distribution in the Northern Hemisphere. Under future scenarios, centroid transfer analysis suggests that its distribution center will shift southwestward, but the potentially suitable habitats in the coastal regions of southern China and northern Indo-China will be lost. These coastal populations should be prioritized for ex situ conservation. Expanding the nature reserve within its long-term stable distribution range in southwest China is an effective strategy for the in situ conservation of the ancient mastixioid flora.

Return to Sports After Anterior Cruciate Ligament Reconstruction.

Anterior cruciate ligament (ACL) tears are one of the most common orthopedic injuries among athletes. Although a small proportion of patients with isolated tears can return to sports after completing a nonsurgical rehabilitation program, ACL reconstruction is frequently recommended for young athletes, especially those with concomitant knee injuries or symptomatic knee instability. Alongside emerging evidence for the effect of prehabilitation, the current standard of care for postoperative ACL physical therapy includes pain control, range of motion, quadriceps strengthening, weight bearing, postoperative bracing, and dynamic limb stabilization and control. The early rehabilitation period includes non-weight-bearing exercises and passive range of motion, which is followed by a longer period of gradual strengthening focused on regaining preinjury strength, proprioception, and control with progressively more demanding dynamic movements. The total rehabilitation period is expected to take around 9 months, during which the patient should be evaluated at frequent intervals by a licensed physical therapist in addition to a daily home exercise program. Prior to discharge from the rehabilitation program, patients should be evaluated by both the surgeon and physical therapist. Patients are encouraged to return to sports once they meet a set of perceptual, subjective, objective, neuromuscular, functional, sport-specific drills, and load management testing criteria.

Hydraulic breakthrough of clay smears due to technical and natural actions

AbstractWe outlined earlier in this journal by means of finite element simulations how patterns of normal faults arise by a synsedimentary tectonic extension, and how clay smears evolve therein. In the present paper, we show how hydraulic breakthroughs of clay smears can arise so that water, gas and mud rise in faults. Mechanical properties of sand and clay are introduced first for the stable range and then for rupture and internal erosion. Our numerical simulations for the evolution of normal faults and clay smears are discussed in light of critical phenomena. Water assembled in an open-cast mine about 20 years ago as the critical hydraulic gradient in a clay smear dropped to the actual one due to the rapid excavation-induced deformation. The latter led to a critical point under an excavation the slope of which was parallel to a nearby normal fault. Clay smears can also break by earthquakes so that the critical hydraulic gradient drops to the actual one caused by methane with an excess pressure. This can lead to hydraulic breakthroughs and cold eruptions at outcrops of faults.

INVESTIGATION OF THE MAP WIDTH IMPROVEMENT IN A RADIALLY REDUCED DIFFUSER DESIGN CONCEPT FOR A CENTRIFUGAL COMPRESSOR

Abstract In order to reduce the compressor cost and weight, a 15% radial reduction was applied to the diffuser passage length of a high pressure ratio centrifugal compressor. The diffuser endwall was diverged to achieve an appropriate area ratio from diffuser inlet to outlet. Two different vane shapes were considered with the radially reduced diffuser passage. The first diffuser vane was a scaled version of the baseline airfoil vane shape and this was used to develop an understanding of the impact of the passage length reduction and diverging endwall. The second vane geometry was parameterized using an unconventional method derived from published literature and optimized to improve performance at DP. The radially reduced designs matched the performance of the baseline configuration. Furthermore, despite not being one of the goals, an extension of the stable operating range of 36% and 20% at the highest speed condition was achieved for the scaled and optimized designs, respectively. The current study focuses on understanding the physical reasons that generated this significant enhancement to the compressor operating range. In order to acquire the desired understanding, experimental data is presented to validate the Computational Fluid Dynamics (CFD) model and a detailed numerical investigation is presented to explain the changes in the flow field within the radially reduced designs. Detailed scrutiny of the flow field revealed a secondary flow feature in the diffuser passage which resulted in higher diffuser passage losses at DP but stabilised the flow as it developed for lower mass flow rate operating points.

Stochastic microstructure modeling and thermal conductivity of coal-based carbon foam

The mechanical, thermal and electrical properties and applications of coal-based carbon foam (CCF) are based on its porous structure. In the present study, a 3-D stochastic numerical program was used to model the microstructure of CCF considering its non-uniformly distributed elliptical pores (i.e., pore dispersity). The heuristic program derived from the foaming process reflected the heterogeneity of foam. Stochastic seeding was used to regulate the pore location dispersity caused by material unevenness and impurities, while the pore size dispersity was revealed by assigning dissolved gas to adjacent pores during pore growth. The structural similarity was confirmed by comparison between the established model and the actual foam in geometrical features, including ligament edge/wall thickness, pore size and ligament cross-section shape etc. The effective thermal conductivity (ETC) of the stochastic model is more sensitive to changes in porosity, compared to that of uniform model of previous literatures. The reason was suspected to be the longer heat transfer path and less cross-section variation of the ligaments of heterogeneous foam. Pore location and size dispersities were regulated in a stable range by program parameters, which indicated that the stochastic model accurately simulated the microstructural complexity of CCF.

Fabrication, physicochemical characterization and theoretical studies of some new mixed ligands complexes based on N-(1H-benzimidazol-2-yl)-guanidine and 1, 10-phenanthroline: DNA interaction, biological applications and molecular docking approach

The fabrication and structural identification of mixed ligand chelates resulting from 1-(1H-benzimidazol-2-yl) guanidine (BIG = main ligand) and 1,10-Phenanthroline (phen) (secondary ligand). The tested compounds were investigated using TGA, CHN, spectra analysis (FT-IR, Mass spectra, NMR), melting point, magnetic moments, molar conductance, Ultraviolet–Visible spectroscopy as well computational studies. The conductance results showed that the tested Pd(II), VO(II) and Ag(I) chelates have electrolytes in fresh solutions of DMSO lies in the range 38.12–118.87 Ω−1 cm2 mol−1 except, Cu(II) chelate is a non-electrolyte it is value equal 15.16 Ω−1 cm2 mol−1. FT-IR spectrum displays that the tested main ligand is coordinated with metal ions in a bi-dentate behavior with N, N donor sites of the HN=C and C=N. While the second ligand coordinated with metal ions through its N2 atom in the pyridine ring. Moreover, the obtained analytical data regarding complexation in solution, molar ratio and continuous variation methods suggest 1M: 1 L molar ratio. Also the stability constant of tested complexes was identified in solution state and the formation constants (Kf) were evaluated by applying continuous-variation method. Stability of complexes was arranged by BIGPAg > BIGPVO > BIGPCu > BIGPPPd in agreement with Kf values. The pH profile revealed that the wide range of pH stability of the tested complexes is at pH = 4- 10 in most of them. Magnetic and electronic spectra are applied to deduce the coordinating ability of the tested ligands and the geometric structure of the studied chelates. That data of magnetic susceptibility for ternary mixed chelates are locked to an octahedral geometry for Cu(II) & VO(II) chelates due to the data of (μeff = 1.8 and 1.83 B.M) respectively and Pd(II) and Ag(I) chelates are diamagnetic with square planar and tetrahedral geometry, respectively. The TGA study of these studied complexes displays that the hydrated H2O, acetate, nitrate, and acetylacetonate anions are removed in the first (45°C-180°C) and second degradation steps followed directly by degradation of the studied ligands in the following stages. The thermodynamic factors, like ΔS*, ΔH*, E*, A and ΔG* are evaluated from the TGA curves and explained. The DFT/B3LYP computation method was applied for the estimation of the MEP, (HUMO & LUMO) energy for the studied compounds. In-silico assay was executed by two different approaches over compounds to evaluate their biological behavior and degree of interaction with biological systems, before practical application. BIGPPd complex displayed priority in interaction with various protein. In-vitro assay was then carried out for compounds against different microbes and BIGPPd showed high antimicrobial activity with inhibition zones are established to be 45.75 ± 0.10 and 41.95 ± 0.05 mm against B. Cereus and G. Candidum at 25 µg/mL. Also, their cytotoxic behavior was examined against MCF-7, HepG2 and HCT-116 carcinoma cell lines, high cytotoxicity was clearly recorded with BIGPPd complex with IC50% are established to be (5, 6.25 and 7.14 µg/mL) respectively. Furthermore, antioxidant activity was examined, and the complexes exhibited high reactivity with trapping free radicals. The BIGPPd exhibited significant free radical scavenging activity with an IC50 value of 20.15 μg/ml. The interaction of metal chelates with DNA was detected by gel electrophoreses, viscosity and spectral studies. Spectrophotometric titration and viscosity studies expose that each of tested complex is an avid binder to DNA. The intrinsic binding constants were calculated for all the tested compounds could bind to Ct-DNA generally through replacement, intercalative mode & minor groove binding of interactions with the sequence: BIGPVO (6.05×104) > BIGPCu > BIGPPd> BIGPAg >BIG (1.16×103). This may be due to enhanced hydrophobic & electrostatic interaction of aromatic rings. Finally, such complexes may be considered as a promising bioactive agent.

Body-centered cubic phase stability in cobalt-free refractory high-entropy alloys

Cobalt-free refractory high-entropy alloys (RHEAs) are strong contenders for structural materials in nuclear reactors because they do not exhibit cobalt activity under irradiation. The mechanical properties and thermal stability of RHEAs are primarily attributed to the solid solution phase, which is essentially the body-centered cubic (BCC) phase. The BCC phase formation rules thus became the basic criterion in the compositional design of RHEAs. In this paper, the BCC phase formation rules in cobalt-free RHEAs were determined via the calculation of six semiempirical parameters, namely, the entropy of mixing, enthalpy of mixing, atomic size difference, Ω-parameter, d-orbital energy level and valance electron concentration. The mixing enthalpy and atomic size differences are more effective than other semiempirical parameters for predicting BCC phase stability in cobalt-free RHEAs. The presence of aluminum is found to cause a notable alteration in the range of phase stability in cobalt-free RHEAs.

Identification of prevalent leachate percolation of municipal solid waste landfill: a case study in India

Landfill leachate forms when waste-inherent water and percolated rainfall transfer are highly toxic, corrosive, acidic, and full of environmental pollutants. The release of leachate from municipal solid waste (MSW) landfill sites poses a severe hazard to human health and aquatic life. This study examined the impact of leachate from Delhi’s Ghazipur landfill on the nearby groundwater quality. Analysis of leachate samples was done to determine various parameters such as total dissolved solids (TDS), hardness, alkalinity, electrical conductivity, pH, BOD5, COD, nitrate, sulphate, chloride and iron, and presence of coliform bacteria. Significant dissolved elements (22,690–34,525 mg/L) were observed in the samples, indicated by the high conductivity value (1156–1405 mho/cm). However, a stable pH range (6.90–7.80) of leachate samples was observed due to high alkalinity concentrations between 2123 and 3256 mg/L. The inverse distance weighing (IDW) interpolation tool from QGIS 3.22.7 developed spatial interpolated models for each parameter across the Ghazipur area. The IDW interpolated graphs of various parameters over the whole study area confirmed these contaminations. In addition, leachate and groundwater samples were physio-chemically analyzed, and temporal fluctuation in landfill waste has also been studied. The temporal fluctuation results showed that when heat is produced, transmitted, and lost throughout the waste system, the maximum temperature position fluctuates over time. The findings of this study highlight the critical importance of landfill management in reducing groundwater contamination from MSW leachate.

Configuration blade shape for enhancement crossflow turbine performance by the CFD method

The pico scale crossflow turbine (CFT) is a prospect as an independent power plant for remote and rural areas because it has a stable efficiency range of 64 % to 79.5 % in high discharge fluctuation. An alternative to CFT performance enhancement is determining the upper blade configuration to increase lift force. Hence, this study investigates four configurations of the upper CFT blade: convex blade at the centre edge, convex at the trailing edge, convex at the leading edge and ordinary curvature. This research employs a computational fluid dynamics (CFD) method to visualise the flow field. The upper CFT blade configuration significantly affects its performance, and convex at the leading edge has higher performance than others. The performance related to each blade shape's specific speed is parabolic and expressed using empirical law. The empirical law recommends 4.88 as specific speed for designing a pico scale CFT.

Effect of surfactant on dynamics and gas-liquid mass transfer for single carbon dioxide bubbles

In carbonation reaction, the impact of surfactants on the movement and mass transfer behavior of carbon dioxide bubbles were crucial for the production of high-quality silicon dioxide products. The study employed the Matlab image processing system to investigate the shapes, motion velocities, and rise path of single carbon dioxide bubbles within varying concentrations of cetyltrimethyl ammonium bromide (CTAB) solutions. This exploration aimed to elucidate the effect of CTAB on the movement and mass transfer coefficient (MTRC) of single carbon dioxide bubbles. Alterations in the CTAB solution concentration and bubble sizes significantly influenced the mass transfer and movement characteristics of single carbon dioxide bubbles. The conclusion was drawn through the computation of the MTRC of single carbon dioxide bubbles in deionized water and CTAB solutions: the addition of CTAB significantly reduced the mass transfer efficiency of carbon dioxide in deionized water, with the MTRC of CTAB solutions decreasing as the solution concentration increased. Utilizing the stagnant cap model, it can be concluded that CTAB's reduction of the MTRC of carbon dioxide was attributed to the high viscosity of the medium, low bubble velocity, stable flow conditions, and intensified adsorption degree of CTAB molecules at the gas-liquid interface. According to the significant periodic trajectories of single carbon dioxide bubbles in the stable range, the correlation between the trajectories of compressible bubbles in surfactant solution and mass transfer in liquid phase was established, and the previous method based on rigid sphere model was modified. The paper proposed the mechanism of CTAB's influence on single carbon dioxide bubbles, offering crucial theoretical insights into the industrial application of surfactants in the carbonation process for producing silicon dioxide.